Carbon tetrachloride (CCl4), is a colorless liquid with a sweet odor. At room temperature, CCl4 exists together a liquid. It has a melting point of around -23 degrees Celcius. That boiling allude is 76 levels Celcius.

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CCl4 is a poisonous gas the depletes the ozone layer and also is frequently known together a greenhouse gas.

It to be a famous solvent in organic chemistry, but, it is rarely offered today since of that adverse health effects.

Henri Victor Regnault, a French chemist, very first produced tetrachloromethane in the year 1839. Chloroform and chlorine were merged to make it.

These days, tetrachloromethane is manufactured by treating methane with chlorine. The following is the reaction:

CH4 (Methane) + 4Cl2 (chlorine) ———> CCl4 + 4 HCl (acid)

Is CCl4 (carbon tetrachloride) a covalent compound? In the following part, we’ll uncover out.

Four chlorine atoms and one carbon atom make up a CCl4 molecule. Since each chlorine atom is one electron brief of one octet construction (complete shell) and carbon is 4 electrons brief of a complete valence covering of eight, 4 chlorine atoms share electrons v the 4 valence electron of carbon, result in complete outer shells because that all 5 atoms.

The bond for this reason formed in between carbon and also chlorine is a covalent bond since it is created by share electrons. This makes CCl4 a covalent compound.


As chlorine and also carbon atom share their outer electrons, chlorine attains the electronic configuration of argon and carbon attains that of neon.

As a result, while creating covalent bond both the chlorine and also carbon atoms basically have external shells through 8 electrons.

Well, that was a fresh answer. Now let me comment on the covalent nature of CCl4 in detail.

Before us dig into the details the covalent bonds in methane, let’s begin from the basics. First, ns will explain the types of bonds.

Ionic bonds

An ionic bond formation takes place as result of the long-term transfer that valence (outermost) electrons of one atom to one more atom.

Electrostatic attraction between positively and also negatively fee ions causes these bonds to form.

The atom which loser electrons i do not care a positively fee ion or cation conversely, the atom i m sorry gains electrons becomes a negatively fee ion or anion.

Covalent Bonds

Elements with incredibly high ionization energies can’t lose electrons, and also those with incredibly low electron affinity can’t accept them.

Such elements’ atoms try to re-superstructure electrons v atoms the other aspects or with the exact same element’s atoms, bring about an octet plan in both valence shells.

A covalent bond deserve to be polar or nonpolar based upon electronegativity difference.

Non-polar covalent bond

A non-polar covalent bond is formed when two atoms share electrons equally. In a non-polar covalent bond, the electronegativity distinction of the bonded atom is usually really small.

It also means that there is no fee separation in between those two atoms or that their electronegativity is identical.

Polar Covalent Bond

A polar covalent shortcut is formed because of the unequal sharing of electron pairs in between two atoms.

According come the Pauling scale, the electronegativity gap between the bonded atoms have to be between 0.4 and 1.7 or about 2.

Factors influence the formation of Covalent Bond

The development of the covalent bond between the atom is affected by several factors as presented below:

Electron affinityIonization energyThe number of valence electronsAtomic sizeElectronegativity

Let me define in information how these factors favor a covalent bond.

Electron affinity

It describes the energy distinction that occurs as soon as an atom profit a valence electron. The formation of a covalent bond is favored when the reacting atoms have comparable electron affinities.

High Ionization Energy

Atoms that have actually high ionization energies choose to kind covalent bonds.

The simple reason is the they can’t form cations. This is due to the fact that it is very challenging for castle to shed their valence electrons, i beg your pardon are needed for ionic bonding.

Chlorine has actually a very high ionization energy of chlorine is 1251.2 kJ/mole if carbon has 1086.5 kJ/mole. Owing to the high ionization enthalpy of both aspects it is simpler to type a covalent bond between them.

Atomic Size

Another property that facilitates the production of a solid covalent link is the smaller sized atomic size.

When it involves forming covalent bonds in between two atoms, the covalent radius is offered to identify how far apart the participating valence electrons of both atoms are.

Each atom’s covalent radius would be fifty percent of the distance between the two nuclei in the instance of developing a covalent radius.

This is the case since an equal variety of valence electron participate and are existing at an equal street from one another, as well as with one equal force of attraction on the various other atom.

As a result, the smaller an atom is, the closer that is come the nucleus. The electrons would be under solid molecular attraction making it challenging for lock to leaving the atom.

So instead of totally transferring the electrons v an ionic bond, the atom would like a covalent bond via share of electrons.

The smaller dimension of both chlorine and also carbon atom facilitates the formation of a covalent bond.


It is one atom’s property that reasons it to attract the shared electron pair in the direction of it. The Pauling range helps us to calculate the electronegativity of the atoms.

Ionic bond are defined as chemical bonds in i beg your pardon the electronegativity difference between two atom in a chemical bond is better than 2.0 (In some texts it is stated as 1.7). If the distinction is much less than 2.0 ~ above the Pauling scale, a covalent bond is present.

Chlorine has an electronegativity of 3.16, and carbon has 2.55. The electronegativity difference in between carbon and hydrogen is 3.16 – 2.55 = 0.61. Due to this difference in electronegativity, the C-Cl link is polar. Together a result, every of the 4 C-Cl bonds has actually a dipole minute value too.

Let’s check out if CCl4 is a polar or non-polar molecule.

The outermost shell of the carbon atom has four electrons, and every one of them take part in the development of covalent bond with 4 chlorine atoms, leave no lone pair ~ above the carbon atom.


With person orbital and three ns orbitals, carbon tetrachloride forms sp3 hybridization. The bond edge in the CCl4 molecule is around 109.5 degrees, creating a tetrahedral geometry.

The tetrahedral molecule geometry that CCl4 cancels the end the dipole moment due to the fact that all 4 bonds (C-Cl) are symmetrical and have one equal fee distribution. Hence CCl4 is non-polar.

The number of Valence Electrons

When every of the combine atoms has 5, 6, or 7 electron in that is valence shell, the formation of a covalent link is preferred. This is why non-metals from the Oxygen, Nitrogen and Halogen households tend to form covalent bonds.

The covalent bonding in carbon is a special case which is described briefly below:

Covalent Bonding in Carbon Atom

To end up being stable, Carbon’s digital configuration demands it to get or lose four electrons, which seems unlikely because:

1. Carbon can’t receive 4 electrons come turn right into a carbon anion (C4-) due to the fact that six protons cannot bring ten electrons, resulting in the atom to end up being unstable.

2. Carbon can not give 4 electrons come turn into a carbocation (C4+) since doing so would take a lot of energy, and also C4+ would only have two electrons preserved by the proton, making that unstable as soon as more.

Since carbon cannot accept or donate electrons, the just option left is sharing electrons to finish its nearest noble gas configuration and thereby kind a covalent bond.

Uses of CCl4

Used together a halogenation solvent and also an commercial fumigant.It’s wonderful source of chlorine because that making chlorine-based organic compounds.Owing to the lack of hydrogen atoms in the CCl4 molecule, that is also useful in NMR spectroscopy.Carbon Tetrachloride is widely supplied in fire extinguishers since it stays clear of fires through extinguishing fire flames.Used in the detection that neutrinos.Used to reveal watermarks top top postage stamps and also in rubber stamp collecting.


Carbon Tetrachloride or CCl4 is a symmetry molecule with 4 chlorine atoms attached to a central carbon atom. It has actually a tetrahedral geometry. Fan to the high electron affinity and small size of carbon and chlorine atom it creates a covalent C-Cl bond.

The link is a polar covalent bond as result of the electronegativity difference. The molecule as a whole is non-polar due to the fact that the dipole moments space canceled out.

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In this article, i have disputed the basic concepts of chemical bonding and also the nature of bond in CCl4. You re welcome feel complimentary to ask any questions girlfriend may have in the comment section. We will certainly respond as soon as possible.